Electrical conductivities of molten zinc chloride – lithium chloride mixtures between 320 and 450 °C
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Redox Potentials of Samarium and Europium in Molten Lithium Chloride
The samarium (III)/(II) and europium (III)/(II) redox potentials in molten lithium chloride were measured using the direct potentiometric method in the temperature range from 923 to 1094 K. Glassy carbon was used as the indifferent working electrode, and the standard chlorine electrode as a reference. The total concentration of rare-earth chlorides dissolved in molten lithium chloride did not e...
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für Naturforschung in cooperation with the Max Planck Society for the Advancement of Science under a Creative Commons Attribution 4.0 International License. Dieses Werk wurde im Jahr 2013 vom Verlag Zeitschrift für Naturforschung in Zusammenarbeit mit der Max-Planck-Gesellschaft zur Förderung der Wissenschaften e.V. digitalisiert und unter folgender Lizenz veröffentlicht: Creative Commons Namen...
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The dependence of indium electro de potential vs. log. concentration of indium (III) is linear and the slopes determined are comparable with the slopes calculated from the Nernst equation, assuming n = 3. The potential of In/ln(III) has been determined to be 0.805 ± 0.003 V with respect to Pt/PtC12 (1 M). At 693 K the free energy of formation of the indium(III) chloride in a 1 M solution is -32...
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Molybdenum(VI) oxide reacts with molten LiC1-KCI eutectie at 450 ~ to form MOO2C12, which probably is present as an anion MoO2Cl4 =, and pyromolybdate, Mo207 =. Both of these species are electrochemically reduced to MOO2, which can be reoxidized to MoO2CI2 by current reversal. A second reduction step, observed whether MoO3 or Mo2072is added to the melt, can be attributed to the reduction of MoO...
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We have developed a new rigid ion model for the simulation of molten ZnCL. A molecular dynamics simulation of this model under a constant pressure of 1 atm and a constant tempera ture of 1200 K resulted in a successful description of the short-range order in the liquid state. The resulting short range structure is presented with respect to the coordination of the Zn 2+ ions and the Z n C I Z n ...
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ژورنال
عنوان ژورنال: Canadian Journal of Chemistry
سال: 1980
ISSN: 0008-4042,1480-3291
DOI: 10.1139/v80-246